When you start interchanging parts, you're juggling many dimensions all at the same time.
First, you can make the hub "over lock nut" distance almost any width by adding or removing lock/spacer washers. From the point of being practical, the smallest "O.L.D." width, that allows your chosen freewheel to clear is best.
Before you go any further, you need to measure and correct the centerline of your rim to the centerline of the hub width. Your wheel was trued to the original hub width, when you changed the hub width (smaller or wider) you changed the centerline of the rim. It needs to be re-trued.
Now you need to move onto the frame alignment. You cannot just cram a wider "O.L.D." hub into a bicycle frame and "know for sure" the bike is in proper alignment. Because the rightside chain stay is indented (dimpled) for the chainwheel and the left side chain stay is not indented the same way, they will not spread equally. The best method to spread the frame is to use a method that allows you to actually measure the frame "Before, During, and After" you do the alignment check, and correction.
Remove the crank from the bicycle, leave the cups pressed into the frame hanger. Mount the frame by the cups into a very large "secured" vise. Use a small string, like a kite string. Tie the string to one rear fork end (fender eyelet), run the string up to the frame head, and back down to the opposite rear fork end ((fender eyelet). Use any kind of a ruler with a metric scale and measure the distance from the string to the seat tube. Then make the same measurement test on the opposite side of the frame. In a perfect world both measurements should be exactly the same. Don't make any corrections yet.
Measure your new hub "O.L.D." and measure the distance between your fork ends. Again, in a perfect world the measurements should be the same. It's much easier to make all of the measurements in metric to make the addition/subtraction easier. You now have the basic information to know which way your frame is "out of alignment", and more importantly, "which way you need to correct it. All you need is a long 2 by 4, longer the better (more leverage). If the right fork end needs to go "in", place the 2 by 4 on the outside of theright fork end and the left side of the seat tube by the bottom bracket housing and apply a small pressure. Since metal "springs back" you have to go past you point slightly. With the frame still in the vise, and the string still in place, just re-measure and see what your correction did to your overall numbers. You can go both In of Out, on either the right side or the left side with this method. No special tools are needed, just a vise, a 2 by 4, and a ruler. You can set the "O.L.D." accurately, and make sure that the new "O.L.D." is centered within the frame centerline. The 2 by 4 sounds crude, but it's the perfect tool because it does not scratch the original paint, does not dent thin wall tubing, and everyone has access to a 2 by 4. Remember, when making corrections, you're subtracting from one side while adding to the opposite side, so you need to make the correction by "one half" the amount.
Here's the last step. A very important final step. With the frame "still in the vise", and "the string still mounted", you need to SQUARE the FORK ENDS in all planes. You can do this most easily with a pair of fork end tools. Park Tool, or Campagnolo are the tools of choice. The same tool is used as both a alignment check, and a bending/correction tool. With the correct tool, this entire step is maybe "two minutes". Using the proper tool allows you to see which side is off, and in which direction. It allows you to correct the misalignment and to not change your desired "O.L.D." If the fork ends are not aligned square to each other, when you tighten the axle nuts the axle will bow and the cone/bearing adjustment will be off.
There's a little more to stuffing a wider hub into a frame than meets the eye.
John